李柏延
特聘研究员，国家级青年人才
地址：天津市海河教育园区同砚路38号南开大学材料科学与工程学院413室
邮箱：libaiyan@nankai.edu.cn
研究方向
新型多孔材料（MOFs,COFs,POCs, HOFs）的设计合成及功能化；光电功能材料设计与开发；功能多孔催化剂创制；吸附分离粉体及膜材料构筑。
个人简介
李柏延，特聘研究员，博士生导师，国家第十五批海外高层次人才获得者，南开大学“百名青年学科带头人”。2010年博士毕业于吉林大学化学学院（导师：施展教授），随后分别在美国南佛罗里达大学Shengqian Ma（马胜前）教授、美国罗格斯大学Jing Li（李静）教授、沙特阿卜杜拉国王科技大学Yu Han（韩宇）教授课题组从事科学研究工作。近年来，以第一及通讯作者身份发表论文50余篇，其中包括Nature Communications，JACS，Angew. Chem.，Chem. Sci.，Chem. Mater.等国际著名期刊杂志，其中 6篇入选 ESI Top 1%高被引论文，论文总引用次数4000多次，获授权发明专利4项。担任海外高层次人才项目、面上基金项目、国家重点研发计划课题负责人等，应邀担任Chinese Chemical Letters青年编委。
主持项目
1、多孔有机框架材料增强传统树脂耐热性及力学性能研究，2022年1月-2023年1月，20万，主持
2、可循环放射性单质碘“纳米陷阱”开发（21978138），国家自然科学基金，2020年1月-2023年12月，79.2万元，主持
3、第15批海外高层次人才，2019年1月-2021年12月，200万元，主持
4、手性多孔晶态催化材料的定向设计和精准构筑（2022YFA1503301），国家重点研发计划，2022年12月-2027年11月，570万，主持
代表作
(1) Xue-Nan Feng, Yi Yang, Xuejie Cao, Ting Wang, De-Ming Kong, Xue-Bo Yin*, Baiyan Li*, Xian-He Bu. A General Approach to Construct CC Single Bond Linked Covalent Organic Frameworks, J. Am. Chem. Soc., 2023, 10.1021/jacs.3c05403.
(2) Zhiyuan Zhang, Xinglong Dong, Jun Yin, Zhi-Gang Li, Xue Li, Daliang Zhang, Tingting Pan, Qiong Lei, Xiongli Liu, Yaqiang Xie, Feng Shui, Jinli Li, Mao Yi, Jin Yuan, Zifeng You, Laiyu Zhang, Jianhong Chang, Hongbo Zhang, Wei Li, Qianrong Fang, Baiyan Li*, Xian-He Bu,* and Yu Han*, Chemically Stable Guanidinium Covalent Organic Framework for the Efficient Capture of Low-Concentration Iodine at High Temperatures, J. Am. Chem. Soc.2022, 144, 6821-6829.
(3) Xiongli Liu, Changjia Zhu, Jun Yin, Jixin Li, Zhiyuan Zhang, Jinli Li, Feng Shui, Zifeng You, Zhan Shi, Baiyan Li*, Xian-He Bu*, Ayman Nafady, Shengqian Ma*, Installation of synergistic binding sites onto porous organic polymers for efficient removal of perfluorooctanoic acid, Nature Communications, 2022, 13, 2132.
(4) Baiyan Li, Xinglong Dong, Hao Wang, Dingxuan Ma, Kui Tan, Stephanie Jensen, Benjamin J. Deibert, Joseph Butler, Jeremy Cure, Zhan Shi, Timo Thonhauser, Yves J. Chabal, Yu Han & Jing Li*, Capture of organic iodides from nuclear waste by metal-organic framework-based molecular traps, Nat. Commun., 2017, 8, 485.
(5) Baiyan Li, Yiming Zhang, Dingxuan Ma, Zhan Shi, Shengqian Ma*, Mercury nano-trap for highly effective and highly efficient removal of mercury(II) from aqueous solution, Nat. Commun.2014, 5, 5537.
(6) Baiyan Li, Kunyue Leng, Yiming Zhang, James J. Dynes, Jian Wang, Yongfeng Hu, Dingxuan Ma, Zhan Shi, Liangkui Zhu, Daliang Zhang, Yinyong Sun*, Matthew Chrzanowski, and Shengqian Ma*, Metal−Organic Framework Based upon the Synergy of a Brønsted Acid Framework and Lewis Acid Centers as a Highly Efficient Heterogeneous Catalyst for Fixed-Bed Reactions. J. Am. Chem. Soc.2015, 137, 4243.
(7) Baiyan Li, Yiming Zhang, Rajamani Krishna, Kexin Yao, Yu Han, Zili Wu, Dingxuan Ma, Zhan Shi, Tony Pham, Brian Space, Jian Liu, Praveen K. Thallapally, Jun Liu, Matthew Chrzanowski, and Shengqian Ma*, Introduction of π Complexation into Porous Aromatic Framework for Highly Selective Adsorption of Ethylene over Ethane, J. Am. Chem. Soc.2014, 136, 8654.
(8) Baiyan Li, Yiming Zhang, Dingxuan Ma, Tianliang Ma, Zhan Shi, and Shengqian Ma*, Metal-Cation-Directed de Novo Assembly of a Functionalized Guest Molecule in the Nanospace of a Metal−Organic Framework, J. Am. Chem. Soc.2014, 136, 1202.
(9) Baiyan Li, Zhijuan Zhang, Yi Li, Kexin Yao, Yihan Zhu, Zhiyong Deng, Fen Yang, Xiaojing Zhou, Guanghua Li, Haohan Wu, Nour Nijem, Yves J. Chabal, Zhiping Lai, Yu Han, Zhan Shi*, Shouhua Feng, and Jing Li*, Enhanced binding affinity, remarkable selectivity, and high capacity of CO2 by dual functionalization of a rht-type metal–organic framework, Angew. Chem. Int. Ed., 2012, 1412.
(10) Baiyan Li, Matthew Chrzanowski, Yiming Zhang and Shengqian Ma*, Applications of Metal-Organic Frameworks Featuring multi-Functional Sites, Coord. Chem. Rev. 2016, 307, 106-129.
(11) Baiyan Li, Yiming Zhang, Dingxuan MaZhenyu Xing, Tianliang Ma, Zhan Shi*, Xiulei Ji and Shengqian Ma*, Creation of a New Type of Ion Exchange Materials for Rapid, High-Capacity, Reversible and Selective Ion Exchange without Swelling and Entrainment, Chem. Sci.,2016, 7, 2138-2144.
(12) Baiyan Li, Dingxuan Ma, Yi Li, Yiming Zhang, Guanghua Li, Zhan Shi*, Shouhua Feng, Michael J. Zaworotko*, and Shengqian Ma*, Dual Functionalized Cages in Metal–Organic Frameworks via Stepwise Postsynthetic Modification, Chem. Mater., 2016, 28 (13), 4781.
(13) Feng Shui, Qiong Lei, Xinglong Dong, Tingting Pan, Zhiyuan Zhang, Jinli Li, Mao Yi, Laiyu Zhang, Xiongli Liu, Zifeng You, Shiqi Yang, Rufeng Ya, Hongbo Zhang, Jixin Li, Zhan Shi, Jun Yin,* Baiyan Li,* Xian-He Bu,* Iodine nanotrap for highly efficient iodine capture under high temperature, Chem. Eng. J. 2023, 468, 143525.
(14) Jinli Li, Qiong Lei, Xinglong Dong, Cailing Chen, Xiongli Liu, Zhiyuan Zhang, Feng Shui, Mao Yi, Baiyan Li,* and Xian-He Bu, Sequential Modification Strategy to Construct Crystalline Benzimidazole Covalent Organic Frameworks with Extraordinary Stability and Polymerization Degree, Chemistry of materials.2023, 35, 4120−4127.
(15) Huaijie Jia, Dingxuan Ma, Shaowei Zhong, Lanjie Li, Lin Li, Lei Xu⁎, Baiyan Li⁎, Boosting Photocatalytic Activity under Visible-light by Creation of PCN-222/g-C3N4 Heterojunctions, Chem. Eng. J. 2019, 368, 165.
(16) Xinyan Zhang, Xinmin Yu, Jixin Li, Lei Xu*, Baiyan Li*, Construction of MOFs/g-C3N4 Composite for Accelerating Visible-Light-Driven Hydrogen Evolution, Int. J. Hydrogen Energ.2022, 47, 18007.
(17) Jianan Liu, Qi Li, Xudong Xiao, Fuxiang Li, Chen Zhao, Qi Sun, Panzhe Qiao, Jing Zhou, Jie Wu, Baiyan Li*, Hongliang Bao, Baojiang Jiang*,Metal-Organic Frameworks Loaded on Phosphorus-Doped Tubular Carbon Nitride for Enhanced Photocatalytic Hydrogen Production and Amine Oxidation, J. Colloid. Interf. Sci.2021, 590, 1.
(18) Baiyan Li, Qi Sun, Yiming Zhang, Carter W. Abney, Briana Aguila, Wenbin Lin, and Shengqian Ma*, Functionalized Porous Aromatic Framework for Efficient Uranium Adsorption from Aqueous Solutions, ACS Appl. Mater. Interfaces 2017, 9, 12511.
(19) Dingxuan Ma, Baiyan Li*,Zhonghua Cui, Kang Liu, Cailing Chen, Guanghua Li, Jia Hua, Benhua Ma, Zhan Shi*, and Shouhua Feng, Multifunctional Luminescent Porous Organic Polymer for Selectively Detecting Iron Ions and 1,4-Dioxane via Luminescent Turn-off and Turn-on Sensing, ACS Appl. Mater. Interfaces 2016, 8, 24097.
(20) Jinli Li, Junhua Wang, Feng Shui, Mao Yi, Zhiyuan Zhang, Xiongli Liu, Laiyu Zhang, Zifeng You, Rufeng Yang, Shiqi Yang, Baiyan Li,* Xian-He Bu, Superhigh intrinsic proton conductivity in densely carboxylic covalent organic framework, Chin. Chem. Lett., 2023, 8, 34,107917.
(21) Dingxuan Ma, Baiyan Li*, Kang Liu, Xianlong Zhang, Weijian Zou, Yongquan Yang, Guanghua Li, Zhan Shi* and Shouhua Feng, Bifunctional MOF Heterogeneous Catalysts Based on The Synergy of Dual Functional Sites for Efficient Conversion of CO2 Under Mild and Co-catalyst Free Conditions, J. Mater. Chem. A 2015, 3, 23136.
(22) Junhua Wang, Xin Lian, Zhiyuan Zhang, Xiongli Liu, Qiao Zhao, Jian Xu, Xichuan Cao,* Baiyan Li,* and Xian-He Bu, Thiazole functionalized covalent triazine frameworks for C2H6/C2H4 separation with remarkable ethane uptake，Chem. Commun, 2023, DOI: 10.1039/d3cc02880a.
(23) Baiyan Li, Youssef Belmabkhout, Yiming Zhang, Prashant M. Bhatt, Hongming He, Daliang Zhang, Yu Han, Mohamed Eddaoudi*, Jason A. Perman and Shengqian Ma*, From an Equilibrium Based MOF Adsorbent to a Kinetic Selective Carbon Molecular Sieve for Paraffin/Iso-Paraffin Separation, Chem. Commun.2016, 52, 13897.
(24) Baiyan Li, Yiming Zhang*, Dingxuan Ma, Liangkui Zhu, Daliang Zhang, Matthew Chrzanowski, Zhan Shi and Shengqian Ma*, Creating Extra Pores in Microporous Carbon via a Template Strategy for a Remarkable Enhancement of Ambient-Pressure CO2 Uptake, Chem. Commun. 2015, 51, 8683.
(25) Baiyan Li, Yiming Zhang, Dingxuan Ma, Lu Li, Guanghua Li, Guo-Dong Li, Zhan Shi* and Shouhua Feng, A Strategy Toward Constructing Bifunctionalized MOF Catalyst: Post-Synthesized Modification of MOFs on Organic Ligands and Coordinatively Unsaturated Metal Sites, Chem. Commun.2012, 48, 6151.
(26) Yiming Zhang, Baiyan Li*, Rajamani Krishna, Zili Wu, Dingxuan Ma, Zhan Shi, Tony Pham, Katherine Forrest, Brian Space and Shengqian Ma*, Highly Selective Adsorption of Ethylene Over Ethane in a MOF Featuring The Combination of Open Metal Site and π-Complexation, Chem. Commun.2015, 51, 2714.
授权发明专利
1、李柏延；张志远。一种高稳定强碱性多孔离子交换材料的制备方法，ZL202110760618.8，2021年07月06日。
2、李柏延；刘雄利.一种利用高压均质制备共价有机框架材料的方法，ZL202110257296.5，2022年05月06日。
3、李柏延；刘雄利.一种利用高压均质制备金属有机框架材料的方法，ZL20211074628.2，2022年11月01日。
4、Functionalized Porous Organic Polymers for Olefin/Paraffin Separations. Shengqian Ma, Baiyan Li, Patent Number: US9511348B2
